A ruthenium tellurocarbonyl (CTe) complex with a cyclopentadienyl ligand: systematic studies of a series of chalcogenocarbonyl complexes [CpRuCl(CE)(H2IMes)] (E = O, S, Se, Te)

Ayumi Suzuki; Takahiro Arai; Kota Ikenaga; Yuichiro Mutoh; Noriko Tsuchida; Shinichi Saito; Youichi Ishii

doi:10.1039/C6DT04440A

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A ruthenium tellurocarbonyl (CTe) complex with a cyclopentadienyl ligand: systematic studies of a series of chalcogenocarbonyl complexes [CpRuCl(CE)(H₂IMes)] (E = O, S, Se, Te)

Ayumi Suzuki, Takahiro Arai, Kota Ikenaga, Yuichiro Mutoh, Noriko Tsuchida, Shinichi Saito and Youichi Ishii
Dalton Trans., 2017,46, 44-48
DOI: 10.1039/C6DT04440A, Communication

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Abstract | Cited by

The first tellurocarbonyl complex with a half-sandwich structure [CpRuCl(CTe)(H₂IMes)] was synthesized by a ligand substitution reaction. The practically complete series of the CpCE complexes [CpRuCl(CE)(H₂IMes)] (E = O, S, Se, Te) were systematically explored. The tellurium atom in the CTe complex could be smoothly replaced with lighter chalcogen atoms.

Graphical abstract: A ruthenium tellurocarbonyl (CTe) complex with a cyclopentadienyl ligand: systematic studies of a series of chalcogenocarbonyl complexes [CpRuCl(CE)(H2IMes)] (E = O, S, Se, Te)

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