NiFeCoCr Medium-entropy Hoffmann-type Coordination Polymer Nanosheet Arrays for Electrocatalytic Urea Oxidation
Abstract
Herein, nickel foam supported NiFeCoCr medium-entropy Hoffmann-type coordination polymer (NiFeCoCr-HCP/NF) nanosheet arrays comprising Ni2+, Co2+, Fe3+, Cr3+, and a potassium tetracyano nickelate ligand were first fabricated. NiFeCoCr-HCP/NF demonstrated superior UOR performance with a low potential of 1.45 V (vs. RHE) at 100 mA cm-2 and a strong operational stability, highlighting Ni-based HCP materials as efficient, economical electrocatalysts.